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We recently demonstrated that SB269652 (1) engages one protomer of a dopamine D2 receptor (D2R) dimer in a bitopic mode to allosterically inhibit the binding of dopamine at the other protomer. Herein, we investigate structural deter minants for allostery, focusing on modifications to three moieties within 1. We find that orthosteric head groups with small 7 substituents were important to… Read more →

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Using the Keck Observatory, O’Donoghue and a team of researchers found charged water particles falling from the planet’s rings into Saturn’s atmosphere. They also found the extent of the ring rain is far greater, and falls across larger areas of the planet, than previously thought. The work reveals the rain influences the composition and temperature structure of parts of Saturn’s… Read more →

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“They asked if I would help them create a whole new vehicle for a very particular situation,” Bangle said. “They were very interested in trying to resolve the megacity problem for people in China, where electric vehicles are really the best alternative. They wanted a vehicle which specifically addressed what happens to people in big cities.”. Nurses see,hear,do and put… Read more →

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Controlling radical intermediates and thus catalysing and directing complex radical reactions is a central feature of S adensosylmethionine (SAM) dependent radical enzymes. We report ab initio and DFT calculations highlighting the specific influence of ion complexation, including Mg2+, identified as a key catalytic component on radical stability and reaction control in 7 carboxy 7 deazaguanine synthase (QueE). Radical stabilisation energies… Read more →

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In addition, structural studies have shown poor replicability and inaccuracy of multiple comparisons over the whole brain. To address these issues, we used the data from a large sample of healthy young adults (776 males and 560 females; mean age: 20.8 years, SD=0.8). We investigated the relationship between CMDT and WMV using the newest version of voxelbased morphometry (VBM). Near… Read more →

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